Spectral properties of cis- and trans-metallooctaethylchlorins: effects of pyrroline ring stereochemistry and macrocyclic conformation

Autor:	Laura A. Andersson, Thomas M. Loehr, Alan M. Stolzenberg, Matthew T. Stershic
Rok vydání:	1990
Předmět:	Tetracoordinate Stereochemistry Pyrroline Ring (chemistry) Resonance (chemistry) Spectral line Inorganic Chemistry chemistry.chemical_compound symbols.namesake Fourier transform chemistry symbols Physical and Theoretical Chemistry Raman spectroscopy Cis–trans isomerism
Zdroj:	Inorganic Chemistry. 29:2278-2285
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00337a020
Popis:	We report herein the resonance Raman, electronic absorption, and Fourier transform intrared (IR) spectra of tetracoordinate Cu II and Ni II complexes of cis- and trans-octaethylchlorin 23 (Figure 1). Both the stereochemistry at the pyrroline ring and the macrocyclic conformation (planar vs S 4 -ruffled) are clearly shown to influence the spectral properties of the M(OEC) complexes
Databáze:	OpenAIRE
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