Luminescence of copper(I) arenethiolates and its relation to copper(I) luminescence in other complexes
Autor: | D. M. Knotter, G. van Koten, G. Blasse, J.P.M. Vliet |
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Rok vydání: | 1992 |
Předmět: | |
Zdroj: | Inorganic Chemistry. 31:2196-2201 |
ISSN: | 1520-510X 0020-1669 |
DOI: | 10.1021/ic00037a038 |
Popis: | The luminescence properties of some trinuclear copper(I) arenethiolates are reported and discussed. Two of these copper(I) arenethiolates, i.e., [CuSC 6 H 4 [(R)-CH(Me)NMe 2 ]-2] 3 and [Cu 3 {SC 6 H 4 [(R)-CH(Me)NMe 2 ]-2} 2 (C≡Ct-Bu)] 2 , show triboluminescence. The optical transitions in these copper(I) compounds are assigned to ligand-to-metal charge transfer (LMCT) |
Databáze: | OpenAIRE |
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