Luminescence of copper(I) arenethiolates and its relation to copper(I) luminescence in other complexes

Autor: D. M. Knotter, G. van Koten, G. Blasse, J.P.M. Vliet
Rok vydání: 1992
Předmět:
Zdroj: Inorganic Chemistry. 31:2196-2201
ISSN: 1520-510X
0020-1669
DOI: 10.1021/ic00037a038
Popis: The luminescence properties of some trinuclear copper(I) arenethiolates are reported and discussed. Two of these copper(I) arenethiolates, i.e., [CuSC 6 H 4 [(R)-CH(Me)NMe 2 ]-2] 3 and [Cu 3 {SC 6 H 4 [(R)-CH(Me)NMe 2 ]-2} 2 (C≡Ct-Bu)] 2 , show triboluminescence. The optical transitions in these copper(I) compounds are assigned to ligand-to-metal charge transfer (LMCT)
Databáze: OpenAIRE