Aluminum, gallium, and indium oxopivalates: Thermodynamic characteristics of gallium oxopivalates

Autor:	N. N. Kamkin, A. V. Steblevskii, A. S. Alikhanyan, D. B. Kayumova, I. A. Dement’ev, N. G. Yaryshev
Rok vydání:	2013
Předmět:	Materials Science (miscellaneous) Metallurgy Analytical chemistry Evaporation chemistry.chemical_element Gas phase Inorganic Chemistry chemistry Aluminium Knudsen number Physical and Theoretical Chemistry Gallium Standard enthalpy change of formation Indium
Zdroj:	Russian Journal of Inorganic Chemistry. 58:839-842
ISSN:	1531-8613 0036-0236
DOI:	10.1134/s0036023613070139
Popis:	Aluminum, gallium, and indium oxopivalates were synthesized by a heterophase method, and their evaporation was studied by the Knudsen effusion method with the mass-spectral analysis of the gas phase. It was shown that oxopivalates can be considered within binary systems as compounds of the type mM(piv)3 · nM2O3. The standard enthalpies of formation of gallium oxopivalates Ga3O(piv)7(gas), 7Ga(piv)3 · Ga2O3(solid), 4Ga(piv)3 · Ga2O3(solid), and 7Ga(piv)3 · 2Ga2O3(solid) were found.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cb4f7e8de9ba445dacd295fbea2a5a8e https://doi.org/10.1134/s0036023613070139 Zobrazit plný text záznamu Full text from SpringerLink