The visible spectrum of fulvene
| Autor: | P.J. Domaille, L.E. Kent, M.F. O'Dwyer |
|---|---|
| Rok vydání: | 1974 |
| Předmět: | |
| Zdroj: | Chemical Physics. 6:66-75 |
| ISSN: | 0301-0104 |
| DOI: | 10.1016/0301-0104(74)80034-0 |
| Popis: | Vapour phase and mixed crystal of the visible band system of fulvene are reported. The spectra show several interesting features including a main progression of 660 cm −1 corresponding to the out-of-plane methylene twisting vibration. Strong Herzberg—Teller origins together with the breadth and overall diffuseness indicate two electronic states of symmetry A 1 and B 2 may be responsible for the observed spectrum. The spectra are blue shifted in going from the vapour to mixed crystal and show sequence structure to the blue of the main bands in the vapour phase. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|