Bi(OTf)3-catalyzed Regioselective Ring Opening of Epoxides with Phenols: Facile Synthesis of 1,3-Diaryloxy-2-propanols
Autor: | Mohammed Naseer Ahmed Khan, Syed Ahmed, Mohammed Arifuddin, Ahmed Kamal, Mahendra Sandbhor |
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Rok vydání: | 2005 |
Předmět: | |
Zdroj: | Chemistry Letters. 34:1142-1143 |
ISSN: | 1348-0715 0366-7022 |
DOI: | 10.1246/cl.2005.1142 |
Popis: | Substituted aryl oxiranes undergo the facile ring opening with phenols in the presence of catalytic amount of bismuth(III) triflate to afford 1,3-diaryloxy-2-propanols in excellent yields under mild conditions. Bismuth(lll) triflate is relatively nontoxic, easy to handle and inexpensive, which makes this procedure particularly attractive for large scale synthesis. |
Databáze: | OpenAIRE |
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