First synthesis and crystal structure of a Mn3+ complex derived from the Ogawa porphyrin-like ligand

Autor:	Corinne Mathoniere, Christian Courseille, Jean-Marc Vincent, Alain Dautant, Jean-Baptiste Verlhac, Ce´line Pierre
Rok vydání:	2001
Předmět:	Structure analysis Stereochemistry Ligand Cyclohexene chemistry.chemical_element General Chemistry Manganese Crystal structure Porphyrin Catalysis chemistry.chemical_compound Crystallography chemistry Materials Chemistry
Zdroj:	New Journal of Chemistry. 25:522-524
ISSN:	1369-9261 1144-0546
Popis:	The synthesis and X-ray structure analysis of a new manganese(III) complex [MnL1(H2O)2]OTf displaying structural analogies with metalloporphyrins are described. This compound is characterized by very short Mn–N bond distances (1.93 A) and a nearly planar structure. Its ability to catalyze cyclohexene epoxidation in the presence of MCPBA has also been evaluated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cb29dc9be5a985e5f897757e472e5f0e https://doi.org/10.1039/b100169h Zobrazit plný text záznamu