Synthesis of an Se-Bridged Triiron Acyl Cluster Complex and the Fischer-Type Carbene Complex Derived from It: Isolation of Rotational Isomers

Autor:	Horng-Sun Chen, Minghuey Shieh, Hsin-Hung Chi, Chuen-Her Ueng
Rok vydání:	2000
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Stereochemistry Cluster (physics) Physical and Theoretical Chemistry Carbene Cis–trans isomerism
Zdroj:	Inorganic Chemistry. 39:5561-5564
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic000301+
Popis:	The synthesis of the acyl cluster complex [Et4N][(μ3-Se)Fe3(CO)9((μ3-η1,η1,η3-C(O)CHCCH2)] and isolation of the trans and cis isomers of the Fischer-type cluster carbene (μ3-Se)Fe3(CO)9(μ3-η1,η1,η3-C(OMe)CHCCH2) are described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cb23a1eb8556a50fbe03673a7c200062 https://doi.org/10.1021/ic000301+ Zobrazit plný text záznamu