Reductive dimerization and oligomerization of alcohols, ketones, and aldehydes to hydrocarbons on a promoted, fused iron catalyst
| Autor: | Glebov Leonid S, Vladimir G. Zaikin, Mikaya Anzor I, G. A. Kliger |
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| Rok vydání: | 2014 |
| Předmět: |
Reaction mechanism
Hydrogen General Chemical Engineering Energy Engineering and Power Technology chemistry.chemical_element General Chemistry Benzaldehyde chemistry.chemical_compound Fuel Technology chemistry Geochemistry and Petrology Benzyl alcohol Reagent Polymer chemistry Organic chemistry Carbon Iron catalyst Space velocity |
| Zdroj: | Petroleum Chemistry. 54:296-308 |
| ISSN: | 1555-6239 0965-5441 |
| DOI: | 10.1134/s0965544114040045 |
| Popis: | A new reductive dimerization and oligomerization reaction of (C5 and C6) cycloalkanols and cycloalkanones, benzaldehyde, and benzyl alcohol to hydrocarbons containing as many, or more, carbon atoms as the reactant oxygenated compound on a promoted, fused iron catalyst proceeds at a temperature of 250–350°C, a hydrogen pressure of 0.1–1 MPa, a specific feed rate of oxygenated reagent of 80–320 g h−1kg−1Ct, and a hydrogen space velocity of 1 × 103 to 20 × 103 h−1. Possible reaction mechanisms have been considered. |
| Databáze: | OpenAIRE |
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