ChemInform Abstract: Palladium-Catalyzed Arylation of α-Allenic Alcohols with Hypervalent Iodonium Salts: Synthesis of Epoxides and Diol Cyclic Carbonates

Autor:	Suk-Ku Kang, Sung-Jae Pyun, Yong-Tack Lee, Tokutaro Yamaguchi, Tae-Gon Baik
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Chemistry Diol Hypervalent molecule chemistry.chemical_element General Medicine Alkylation Medicinal chemistry Catalysis Palladium
Zdroj:	ChemInform. 29
ISSN:	1522-2667 0931-7597
Popis:	Pd(0)-catalyzed arylation of the aryl-substituted α-allenic alcohols with hypervalent iodonium salts afforded substituted trans-epoxides. Alternatively, arylation of the alkyl-substituted α-allenic alcohols in the presence of K 2 CO 3 afforded syn-diol cyclic carbonates and trans-epoxides in the presence of Cs 2 CO 3 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cacdcb60bb7e6ec045f11f0441283e05 https://doi.org/10.1002/chin.199827050 Zobrazit plný text záznamu Plný text