Reaction of tetrahydrofuran with H2S in the presence of Na+/γ-Al2O3

Autor: I. V. Desyatov, A. V. Mashkina, E. A. Paukshtis
Rok vydání: 1993
Předmět:
Zdroj: Reaction Kinetics & Catalysis Letters. 51:45-50
ISSN: 1588-2837
0133-1736
Popis: Modification of γ-Al2O3 by sodium hydroxide promotes the increase of surface basicity but does not exert a strong effect on catalytic activity in the reaction of thiolane production from tetrahydrofuran and H2S. Introduction of NaOH to γ-Al2O3 in small concentration increases the number of Lewis acid centers but decreases their strength. The activity of Na/γ-Al2O3 referred to one Lewis acid center drops.
Databáze: OpenAIRE