Mechanism of selective oxidation of methanol over stannic oxide-molybdenum oxide catalyst

Autor:	J. Tichý, Jaroslav Machek, Václav Lochař
Rok vydání:	2002
Předmět:	Reaction mechanism Methyl formate Process Chemistry and Technology Inorganic chemistry Oxide chemistry.chemical_element Heterogeneous catalysis Catalysis chemistry.chemical_compound chemistry Molybdenum Formate Methanol
Zdroj:	Applied Catalysis A: General. 228:95-101
ISSN:	0926-860X
DOI:	10.1016/s0926-860x(01)00970-x
Popis:	The mechanism of the selective oxidation of methanol on Sn-Mo oxide catalyst with molar ratio Mo/(Mo + Sn) = 0.3 is investigated. The interaction of methanol and its oxidation products (i.e. formaldehyde and methyl formate) is studied by FT-IR spectroscopy. The data are interpreted on the basis of a reaction mechanism which contains 10 elementary steps. The behaviors of the surface species (methoxy, formate and dioxymethylene groups) are compared with those monitored on other systems and the catalyst requirements for the title reaction are discussed. © 2002 Elsevier Science B.V. All rights reserved.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::caad5a6216705b850c2a5b394c3b22c7 https://doi.org/10.1016/s0926-860x(01)00970-x Zobrazit plný text záznamu Full Text from ScienceDirect