Spectra and structure for Bi0-BiCl3-Li, K/Cl

Autor:	C. V. Volkov, V. F. Kozin, N. I. Buryak, I. A. Sheka
Rok vydání:	1991
Předmět:	Esr spectra Crystallography Unpaired electron chemistry medicine chemistry.chemical_element General Chemistry Chloride Spectral line Ion Bismuth medicine.drug
Zdroj:	Theoretical and Experimental Chemistry. 27:270-273
ISSN:	1573-935X 0040-5760
DOI:	10.1007/bf01372492
Popis:	Raman-scattering, electronic-absorption, and ESR spectra have been used to determine the states of bismuth and the structures of the compounds formed in molten chloride systems; it is found that BiCl4− with Td symmetry are formed in BiCl3-Li, K/Cleu melts, while a Bi0-BiCl3-Li, K/Cleu melt produces the BiCl4− ⇄ BiCl3 + Cl−; BiCl3 + Bi0 ⇄ Bi2Cl3 equilibria with the formation of Cl− the quasitetrahedral ion in the second stage, which has a metal-bond and a single unpaired electron.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ca82094f12c7b305f2760c9aaf2415ed https://doi.org/10.1007/bf01372492 Zobrazit plný text záznamu Full text from SpringerLink