Condensation Reaction of Ferrocene with Carbonyl Compounds

Autor:	Mikio Shiga, Izumi Motoyama, Kazuo Hata
Rok vydání:	1968
Předmět:	chemistry.chemical_classification Olefin fiber Ketone Cyclohexanone General Chemistry Condensation reaction Medicinal chemistry chemistry.chemical_compound chemistry Propiophenone Ferrocene Acetone Organic chemistry Acetophenone
Zdroj:	Bulletin of the Chemical Society of Japan. 41:1891-1896
ISSN:	1348-0634 0009-2673
DOI:	10.1246/bcsj.41.1891
Popis:	The condensation reactions of ferrocene with various ketones and with trichloroacetaldehyde in the presence of aluminum chloride were investigated. The formation of carbinol (7) as an intermediate was postulated in these reactions. In the reaction of acetone with ferrocene, the intermediate carbinol underwent further condensation with other ferrocene molecules to give oligomers (9). On the other hand, in the cases of methyl ethyl ketone, acetophenone, propiophenone, cyclohexanone, and trichloroacetaldehyde, the condensation reactions produced olefinic compounds via the intermediate carbinols. The intermediate carbinol was isolated together with the olefin in the reaction with trichloroacetaldehyde.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ca7b47933d0ca9c2b6c2e4e7170aeae7 https://doi.org/10.1246/bcsj.41.1891 Zobrazit plný text záznamu