Square-Planar Silver(I)-Containing Polymers Formed from π-Stacked Entities

Autor:	Lyall R. Hanton,† and, Aidan G. Young
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Stereochemistry Ligand General Chemistry Polymer Condensed Matter Physics Square (algebra) Dibenzofuran chemistry.chemical_compound Crystallography Planar chemistry Reaction sequence General Materials Science
Zdroj:	Crystal Growth & Design. 6:833-835
ISSN:	1528-7505 1528-7483
DOI:	10.1021/cg0506267
Popis:	The flexible ligand 4,6-bis(3‘-pyridylmethylsulfanyl)dibenzofuran (L) was synthesized in a three-step reaction sequence. This new ligand was complexed with both AgClO4 and AgNO3, in a 1:2 metal-to-ligand ratio. The isomorphous structures were one-dimensional coordination polymers each containing a rare square-planar Ag(I) connector. The X-ray structures showed numerous π interactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ca7b442e44b1daffade6f279740ffd53 https://doi.org/10.1021/cg0506267 Zobrazit plný text záznamu