Interaction of ZnO surfaces with oxygen after illumination in the presence of CO and O2

Autor:	J. Łagowski, C.L. Balestra, Harry C. Gatos, R.P. Holmstrom
Rok vydání:	1978
Předmět:	Inert Orders of magnitude (temperature) Inorganic chemistry chemistry.chemical_element Surfaces and Interfaces Condensed Matter Physics Photochemistry Oxygen Surfaces Coatings and Films Ion Electron transfer chemistry Chemisorption Thermal Materials Chemistry Carbon
Zdroj:	Surface Science. 76:L575-L579
ISSN:	0039-6028
DOI:	10.1016/0039-6028(78)90115-2
Popis:	It was found that oxygen chemisorption on ZnO surfaces is accelerated by as much as three orders of magnitude after illumination in the presence of CO + O 2 . This accelerated chemisorption is characterized by electron transfer and thermal activation as is oxygen chemisorption on “real” ZnO surfaces. The observed behavior is attributed to the formation of surface complexes (involving carbon, oxygen and Zn ions) which enhance oxygen chemisorption. These complexes are stable at room temperature and render the surface inert to further CO-interaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ca6b3daa9b2c74e93c824f4873add0c6 https://doi.org/10.1016/0039-6028(78)90115-2 Zobrazit plný text záznamu