Structure of products of H-H and C-H bond activation by Ni atom, Ni2 cluster, and Ni-porphyrin complex of Ni2 cluster

Autor:	V. M. Mamaev, E. V. Zernova, Dmitry A. Lemenovskii, Igor P. Gloriozov
Rok vydání:	2000
Předmět:	C h bond Hydrogen chemistry.chemical_element General Chemistry Photochemistry Porphyrin Catalysis Methane Computer Science Applications chemistry.chemical_compound Crystallography chemistry Modeling and Simulation Atom Cluster (physics)
Zdroj:	Kinetics and Catalysis. 41:33-37
ISSN:	1608-3210 0023-1584
DOI:	10.1007/bf02756137
Popis:	New catalytic systems based on porphyrin complexes of Ni2 cluster and capable of activating C-H and H-H bonds are proposed. DFT calculations showed that a Ni2 cluster can coordinate Ni-porphyrin with a considerable gain in energy. The structures of the products of methane and hydrogen activation were discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ca6b02a2a07d38df4f58dbfbc3d271af https://doi.org/10.1007/bf02756137 Zobrazit plný text záznamu Full text from SpringerLink