Migration of alkylthio group during cleavage of thiols from 1,1,3-tris (alkylthio) propanes

Autor:	V. I. Kaigorodova, A. S. Atavin, Al'bina I. Mikhaleva, E. G. Chebotareva, Boris A. Trofimov, V. A. Pestunovich
Rok vydání:	1973
Předmět:	Tris chemistry.chemical_compound Chemistry Group (periodic table) Stereochemistry Potassium chemistry.chemical_element General Chemistry Cleavage (embryo) Medicinal chemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 22:2276-2278
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf01199629
Popis:	1. 1,3-Di (alklythio)-1-propenes are formed predominantly when alkanethiols are cleaved from 1,1,3tris(alkylthio)propanes in the presence of diethyl phosphite or potassium tert-butoxide. 2. The elimination is accompanied by migration of the alkylthio group, and leads to the formation of 1,2-di(alkylthio)-1-propenes.
Databáze:	OpenAIRE
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