ChemInform Abstract: Enantioselective Synthesis of 6-Oxygenated Atisine Derivative via Intramolecular Double Michael Reaction

Autor:	Akihito Hirabayashi, Masataka Ihara, Keiichiro Fukumoto, Nobuaki Taniguchi
Rok vydání:	2010
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Addition reaction Ketone Chemistry Stereochemistry Intramolecular force Michael reaction Enantioselective synthesis General Medicine Aldehyde Enone Derivative (chemistry)
Zdroj:	ChemInform. 23
ISSN:	0931-7597
DOI:	10.1002/chin.199240258
Popis:	An enantioselective synthesis of a 6-oxygenated atisine derivative 20 is described. The atisine skeleton 18 was stereoselectively constructed by the intramolecular double Michael reaction of the enone ester 16, derived, through the aldehyde 3, from the symmetrical ketone 4.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ca3cb0afda1ec7f869dd56c2be6f6d55 https://doi.org/10.1002/chin.199240258 Zobrazit plný text záznamu Plný text