The structural characterisation of Ph3PSe(Ph)I. The first charge transfer (CT) complex of a tertiary phosphine containing a pseudohalogen
| Autor: | Joanne M. Sheffield, Charles A. McAuliffe, Philip D. Boyle, Robin G. Pritchard, Stephen M. Godfrey |
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| Rok vydání: | 1999 |
| Předmět: |
Metals and Alloys
Charge (physics) General Chemistry Photochemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Yield (chemistry) Pseudohalogen Polymer chemistry Materials Chemistry Ceramics and Composites Triphenylphosphine Phosphine |
| Zdroj: | Chemical Communications. :2159-2160 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/a906039a |
| Popis: | The reaction of 2 mol equivalents of triphenylphosphine with diphenyldiselenyldiiodine (Ph2Se2I2) produces the charge transfer (CT) complex Ph3PSe(Ph)I in quantitative yield; this compound represents the first report of a CT complex of a tertiary phosphine that contains a pseudohalogen. |
| Databáze: | OpenAIRE |
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