ChemInform Abstract: TEMPO-Mediated Oxidation of Primary Alcohols to Aldehydes under Visible Light and Air

Autor:	Hongxia Zhou, Pixu Li, Xiaoqin Shen, Dongwang Liu, Xiangyong Gu
Rok vydání:	2014
Předmět:	Primary (chemistry) Chemistry Homogeneous General Medicine Molecular oxygen Photochemistry Visible spectrum
Zdroj:	ChemInform. 45
ISSN:	0931-7597
DOI:	10.1002/chin.201429083
Popis:	A homogeneous visible light photoredox TEMPO-mediated selective oxidation of primary alcohols to the corresponding carbonyl compounds was developed using molecular oxygen from air as the terminal oxidant. Ru(bpy)3(PF6)2 (bpy: bipyridyl) and Ir(dtb-bpy)(ppy)2(PF6) (dtb-bpy: 4,4′-di-tert-butyl-2,2′-bipyridyl; ppy: 2-phenylpyridine) were used as the sensitizers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ca0ce5075125ace852cd4e97cfc6aa96 https://doi.org/10.1002/chin.201429083 Zobrazit plný text záznamu Plný text