Potential Drop Based Model to Analyze Electrode Passivation by Fouling from Phenolic Compounds
Autor: | Xiaoyun Yang, Aleksandr Simonian, Jeffrey Kirsch, Yuanyuan Zhang, Jeffrey W. Fergus |
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Rok vydání: | 2013 |
Předmět: | |
Zdroj: | ECS Transactions. 53:1-14 |
ISSN: | 1938-6737 1938-5862 |
DOI: | 10.1149/05335.0001ecst |
Popis: | Dielectric interface would be formed on the electrode surface during the analysis or disposal of many phenolic compounds due to electro-polymerization. This could cause electrode passivation, or called electrode fouling, which is indicated by the continuously decaying current signal. This paper proposed a model based on the potential drop across the fouling layer, which is helpful for deep understanding of the electrode passivation/fouling process. This model successfully fitted the experimental results. |
Databáze: | OpenAIRE |
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