Heterodinuclear bis(diphenylphosphino)methane-bridged molybdenum(d6)-palladium(d8) complexes with dative Mo.fwdarw.Pd bonding
| Autor: | Bruce C. Noll, Marilyn M. Olmstead, Alan L. Balch, Dawn V. Toronto |
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| Rok vydání: | 1993 |
| Předmět: |
Diketone
Inorganic chemistry chemistry.chemical_element Crystal structure Medicinal chemistry Inorganic Chemistry Metal chemistry.chemical_compound chemistry Molybdenum visual_art X-ray crystallography visual_art.visual_art_medium Molecule Physical and Theoretical Chemistry Dichloromethane Palladium |
| Zdroj: | Inorganic Chemistry. 32:3613-3619 |
| ISSN: | 1520-510X 0020-1669 |
| Popis: | Investigation of the reaction between (t-BuNC) 2 PdCl 2 and mer-Mo(dpm-P,P')(dpm-P)(CO) 3 (dpm=bis-(diphenylphospbino)methane) has produced two complexes that combine a d 6 and a d 8 metal center. The reaction in dichloromethane yields green [(t-BuNC)(OC) 3 Mo(μ-dpm) 1 PdCl]Cl |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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