Reactions of Tungsten Alkylidynes with Thionyl Chloride
| Autor: | David J. Williams, and Andrew J. P. White, Anthony F. Hill, Darren J. Cook, Stephen Anderson, John M. Malget |
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| Rok vydání: | 2004 |
| Předmět: |
Tungsten Compounds
Chemistry Organic Chemistry chemistry.chemical_element Halogenation Nuclear magnetic resonance spectroscopy Crystal structure Tungsten Inorganic Chemistry Chemical kinetics chemistry.chemical_compound Thionyl chloride Polymer chemistry Molecule Organic chemistry Physical and Theoretical Chemistry |
| Zdroj: | Organometallics. 23:2552-2557 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/om030691i |
| Popis: | The reaction of [W(⋮CR)(CO)2(η-C5H5)] (R = C6H3Me2-2,6) with thionyl chloride provides the metallacyclic alkylidene complex [W(CRSCRS)Cl3(η-C5H5)], while similar treatment of [W(⋮CR)(CO)2{HB(pz)3}]... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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