Role of Molecular Modeling in the Development of CO2–Reactive Ionic Liquids
| Autor: | William F. Schneider, Quintin R. Sheridan, Edward J. Maginn |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Molecular interactions
Molecular model Chemistry Nanotechnology 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Chemical functionalization Ionic liquid 0210 nano-technology |
| Zdroj: | Chemical Reviews. 118:5242-5260 |
| ISSN: | 1520-6890 0009-2665 |
| DOI: | 10.1021/acs.chemrev.8b00017 |
| Popis: | Ionic liquids (ILs) have gained considerable attention in recent years as CO2-reactive solvents that could be used to improve the economic efficiency of industrial-scale CO2 separations. Researchers have demonstrated that IL physical and chemical properties can be optimized for a given application through chemical functionalization of both cations and anions. The tunability of ILs presents both a great potential and a significant challenge due to the complex chemistries and the many ways in which ILs can be made to react with CO2. However, computer simulations have demonstrated great potential in understanding the behavior of ILs from the underlying molecular interactions. In the present review, we examine how computer simulations have aided in the design of ILs that chemically bind CO2. We present the historical development of CO2-reactive ILs while highlighting the insights provided by molecular modeling which aided in understanding IL behavior to further experimental findings. We also provide a brief d... |
| Databáze: | OpenAIRE |
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