N-Hydroxyhomoazaadamantanone and its complexes with dioxo-molybdenum(VI) and copper(II): synthesis and structure

Autor:	Lyudmila I. Koval, Valeriy I. Dzyuba, V. I. Pekhnyo, Anatolij V. Dudko
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Copper complex 1h nmr spectroscopy Hydroxamic acid Stereochemistry Hydrochloride chemistry.chemical_element Copper Medicinal chemistry Coordination complex chemistry.chemical_compound chemistry Molybdenum Materials Chemistry Molecule Physical and Theoretical Chemistry
Zdroj:	Journal of Coordination Chemistry. 67:1437-1448
ISSN:	1029-0389 0095-8972
DOI:	10.1080/00958972.2014.910598
Popis:	A hydroxamic acid of a new type, N-hydroxyhomoazaadamantanone (HL), has been synthesized, combining several structure peculiarities: cage skeleton, heterocyclicity, and rigidly fixed cis-orientation of the oxygens of the hydroxamate fragment of the molecule. Complexes of HL with dioxo-molybdenum(VI) ((MoO2LC2H5OH)2O) and copper(II) (CuL2) have been synthesized. All compounds were characterized by IR and 1H NMR spectroscopy. X-ray structural analyses of N-hydroxyhomoazaadamantanone hydrochloride and the coordination compounds have been carried out.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c9ad967a9c7e45c753626a2850428214 https://doi.org/10.1080/00958972.2014.910598 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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