Application of Br-82 as a radioactive tracer isotope to study bromide ion-isotopic exchange reaction in strongly basic anion exchange resin Duolite A-161

Autor:	Ram S. Lokhande, Pravin U. Singare, S. R. D. Tiwari
Rok vydání:	2009
Předmět:	Radioactive tracer Kinetics Radiochemistry Reversible reaction law.invention Ion Chemical kinetics Reaction rate chemistry.chemical_compound chemistry Bromide law Physical and Theoretical Chemistry Ion-exchange resin Nuclear chemistry
Zdroj:	Russian Journal of Physical Chemistry A. 83:1389-1394
ISSN:	1531-863X 0036-0244
Popis:	In the present investigation Br-82 radioactive isotope was used as a tracer to study the kinetics of exchange reaction taking place between the ion exchange resin and the external bromide ion solution. In an attempt to study the reversible bromide ion-isotopic exchange reaction kinetics, it was expected that whether the initial step was the exchange of radioactive bromide ions from the solution on to the ion exchange resin (forward reaction), or from the ion exchange resin in to the solution (reverse reaction), the two ion-isotopic exchange reactions should occur simultaneously, which was further confirmed from the values of specific reaction rate 0.122 and 0.123 min−1 respectively obtained under identical experimental conditions. The radioactive tracer technique employed in the present investigation will be useful for characterization of various industrial grade ion exchange resins.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c99e91dc08383176c5f4d96cec81ae44 https://doi.org/10.1134/s003602440908024x Zobrazit plný text záznamu Full text from SpringerLink