Evaluation of new organoclay stationary phases for the separation of ethylbenzene and xylene isomers

Autor:	Albert Zlatkis, J. Jiao
Rok vydání:	1991
Předmět:	Resolution (mass spectrometry) Component (thermodynamics) Organic Chemistry Clinical Biochemistry Xylene Biochemistry Ethylbenzene Analytical Chemistry chemistry.chemical_compound chemistry Structural isomer Organoclay Organic chemistry Gas chromatography Selectivity
Zdroj:	Chromatographia. 31:457-464
ISSN:	1612-1112 0009-5893
DOI:	10.1007/bf02262389
Popis:	Several kinds of Bentones which have structures similar to Bentone 34 have been tested and compared for the purpose of improving the resolution of ethylbenzene and xylene isomers by gas chromatography. Bentone SD-3 was found to have higher selectivity toward these close-boiling compounds than the well known stationary phase Bentone 34. Modification effects of some conventional stationary phases which represent the whole range of polarity on the chromatographic property of Bentone SD-3 have been investigated and discussed. A number of new organoclays which have different structures of the organic cation in complexes have been synthesized and their properties evaluated for the separation of positional isomers. A simultaneously high selective organoclay for each component in the aromatic mixture of ethylbenzene and xylene isomers, without assistance of conventional stationary phases, has been described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c98bc110059ede956a3b50a0f6730ec5 https://doi.org/10.1007/bf02262389 Zobrazit plný text záznamu Full text from SpringerLink