Structure of the 1:1 complex of dimethyl sulfoxide with hydroquinone: Supramolecular architecture based on D-H⋯A hydrogen bonds (D = O, C; A = O, π)

Autor:	K. A. Khaldoyanidi, T. M. Polyanskaya
Rok vydání:	2008
Předmět:	Hydroquinone Hydrogen bond Chemistry Dimethyl sulfoxide Stereochemistry Supramolecular chemistry Crystal structure Triclinic crystal system Supramolecular assembly Inorganic Chemistry Crystallography chemistry.chemical_compound Materials Chemistry Molecule Physical and Theoretical Chemistry
Zdroj:	Journal of Structural Chemistry. 49:327-334
ISSN:	1573-8779 0022-4766
DOI:	10.1007/s10947-008-0131-3
Popis:	The hydroquinone-dimethyl sulfoxide-toluene system was investigated by thermal and X-ray diffraction analyses. The crystal structure of the 1:1 complex of hydroquinone with dimethyl sulfoxide was determined. Crystal data: C8H12O3S, M = 188.24, triclinic system, space group P1¯, unit cell parameters: a = 7.4202(2) A, b = 8.4046(3) A, c = 8.7340(3) A; α = 100.830(1)°, β = 99.794(1)°, γ = 114.129(1)°; V = 469.35(4) A3, Z = 2, d calc = 1.332 g/cm3, R1 = 0.028, T = 100 K. The molecules are linked in a supramolecular assembly via D-H...A hydrogen bonds (D = O, C; A = O, π).
Databáze:	OpenAIRE
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