Access to Substituted Thiophenes through Xanthate-Mediated Vinyl C(sp2)-Br Bond Cleavage and Heterocyclization of Bromoenynes

Autor: Peng Zhou, Lu Chen, Shaohua Jiang, Minghua Sun, Jiaming Li, Guoling Huang, Jian Li, Jianrong Li, Yibiao Li, Yubing Huang
Rok vydání: 2020
Předmět:
Zdroj: The Journal of Organic Chemistry. 85:13037-13049
ISSN: 1520-6904
0022-3263
DOI: 10.1021/acs.joc.0c01733
Popis: An environmentally sustainable strategy for the chemoselective heterocyclization of bromoenynes through a transition-metal-free sulfuration/cyclization process is reported. Using inexpensive and sa...
Databáze: OpenAIRE