Electrical properties of dendritic macromolecule containing azo-groups

Autor:	Burm-Jong Lee, Chungkyun Kim, Seung-Yeop Yoo, Ki-Sung Yang, Sung-Hyun Jung, Young-Soo Kwon
Rok vydání:	2004
Předmět:	Materials science Stereochemistry Light irradiation General Chemistry Condensed Matter Physics Surface pressure Metal chemistry.chemical_compound Crystallography Azobenzene chemistry visual_art Dendrimer Monolayer visual_art.visual_art_medium General Materials Science Thin film Macromolecule
Zdroj:	Molecular Crystals and Liquid Crystals. 425:249-255
ISSN:	1563-5287 1542-1406
Popis:	We synthesized the G4-48Azo dendrimer functionlized with azobenzene groups, fully reversible photo-isomerization reaction, in their periphery. We investigated monolayer behavior and its characteristics at air-water interface by LB method. And we observed the difference of molecular behavior and measured the surface pressure shift by 365[nm]light irradiation because of the photo-isomerization of the azobenzene group in their periphery. The electrical properties of the G4-48Azo dendrimer were compared with between trans form and cis form using metal/dendrimer LB film/metal(MIM)structure and STM system. And we obtained the difference of values in I-V characteristics using STM originating from the photo-isomerization of the azobenzene.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c94839ba4767e2bceaf32fec8dcdc6be https://doi.org/10.1080/15421400490506892 Zobrazit plný text záznamu