Final purification of uranium-233 oxide product from reprocessing treatment of irradiated thorium rods

Autor: A. Palamalai, R. Srinivasan, P. Govindan, V. R. Raman, G. R. Balasubramanian, M. Sampath, S. V. Mohan, A. Chinnusamy
Rok vydání: 1994
Předmět:
Zdroj: Journal of Radioanalytical and Nuclear Chemistry Articles. 177:291-299
ISSN: 1588-2780
0236-5731
DOI: 10.1007/bf02061125
Popis: Some batches of233U oxide product obtained from the reprocessing treatment of irradiated thorium rods, called J-rods in our plant, have been found to contain thorium as much as 85% and iron above 5% as impurities. This product has to be purified before sending for fabrication of the fuel. The present purification method consists of the following three steps: (1) preferential dissolution of U3O8 as compared to thoria, (2) a novel solvent extraction process, and (3) preferential precipitation of Th as oxalate leaving behind the entire U in the filtrate. Development and application of the present purification method to the above233U oxide proxduct are presented in this paper.
Databáze: OpenAIRE