Influence of solvent reorientation dynamics upon the kinetics of some electron-exchange reactions

Autor:	Michael J. Weaver, Thomas Gennett
Rok vydání:	1985
Předmět:	Solvent Electron transfer genetic structures Chemistry Kinetics Electron exchange General Physics and Astronomy Physical and Theoretical Chemistry Electrochemistry Photochemistry behavioral disciplines and activities Redox
Zdroj:	Chemical Physics Letters. 113:213-218
ISSN:	0009-2614
Popis:	The role of solvent reorientation dynamics is explored for outer-sphere electron transfer by examining the solvent-dependent rates for electrochemical exchange of selected organometallic redox couples. The observations are consistent with the anticipated variations in the solvent reorientation frequency. The implications of these findings to other reactions involving only small bond distortions are noted.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c9261de27794396b6c315aaadbe9dd43 https://doi.org/10.1016/0009-2614(85)80944-1 Zobrazit plný text záznamu