Autor: |
Michael J. Weaver, Thomas Gennett |
Rok vydání: |
1985 |
Předmět: |
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Zdroj: |
Chemical Physics Letters. 113:213-218 |
ISSN: |
0009-2614 |
Popis: |
The role of solvent reorientation dynamics is explored for outer-sphere electron transfer by examining the solvent-dependent rates for electrochemical exchange of selected organometallic redox couples. The observations are consistent with the anticipated variations in the solvent reorientation frequency. The implications of these findings to other reactions involving only small bond distortions are noted. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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