Synthesis, 89Y and 51V-NMR of Er-doped zircon-type YVO4 and LUVO4

Autor: R. Amantea, V. Tartara, Paolo Ghigna, Piercarlo Mustarelli
Rok vydání: 2005
Předmět:
Zdroj: Journal of Solid State Chemistry. 178:1692-1696
ISSN: 0022-4596
DOI: 10.1016/j.jssc.2005.03.014
Popis: Y 0.99 Er 0.01 VO 4 and Lu 0.99 Er 0.01 VO 4 zircon-type compounds have been synthesized by solid-state reaction starting from the parent oxides. The obtained materials are single phase, well crystallized and homogeneous in the chemical composition. The magic angle spinning-NMR characterization points toward the substitutional nature of erbium on the rare earth site. The isotropic chemical shift of 89 Y in an orthovanadate is reported for the first time.
Databáze: OpenAIRE