Hetaryladamantanes communication 4. Synthesis, structure, and properties of 6-(1-adamantyl)-3-cyanopyridine-2(1H)-thione

Autor: Yu. A. Sharanin, V. N. Nesterov, Yu. T. Struchkov, V. P. Litvinov, E. E. Apenova, V. E. Shklover
Rok vydání: 1986
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 35:131-139
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00952860
Popis: 1. 6-(1-Adamantyl)-3-cyanopyridine-2(1H)-thione, a convenient synthon for the preparation of adamantyl-substituted thieno[2,3-b]pyridines, has been obtained for the first time. 2. Alkylation of the pyridinethione has given 2-mercapto-substituted 6-(1-adamantyl)-3-cyanopyridines, which cyclize in the presence of bases to 2-substituted-6-(1-adamaiityl)-3-aminothieno[2,3-b]pyridines. 3. The structure of bis[6-(1-adamantyl)-3-cyanopyrid-2-yl] disulfide has been confirmed by an x-ray structural examination.
Databáze: OpenAIRE
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