The palladium-catalyzed synthesis of diphenyl carbonate from phenol, carbon monoxide, and oxygen
| Autor: | Robert Owen Matthews, G.M. Lucas, John E. Hallgren |
|---|---|
| Rok vydání: | 1981 |
| Předmět: |
inorganic chemicals
Tertiary amine Organic Chemistry Inorganic chemistry chemistry.chemical_element Vanadium Manganese Biochemistry Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Diphenyl carbonate Materials Chemistry Physical and Theoretical Chemistry Cobalt Palladium Carbon monoxide |
| Zdroj: | Journal of Organometallic Chemistry. 204:135-138 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)82481-x |
| Popis: | Diphenyl carbonate was obtained from the reaction of carbon monoxide, phenol, and oxygen using catalytic quantities of palladium, a tertiary amine, and an oxidation cocatalyst at room temperature and atmospheric pressure. A variety of copper, vanadium, cobalt, and manganese salts were effective cocatalysts, although in many cases side products were produced. Using catalytic quantities of manganese salts, up to 100 mol of diphenylcarbonate per mol of palladium was realized. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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