Deprotonated bis(diphenylphosphino)methane as a monodentate C-bonded ligand: preparation and 31P/199Hg NMR characterisation of Hg[CH(PPh2)2]2
| Autor: | Paul Peringer, Maria Lusser |
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| Rok vydání: | 1986 |
| Předmět: |
Denticity
Ligand Stereochemistry Organic Chemistry chemistry.chemical_element Nuclear magnetic resonance spectroscopy Biochemistry Medicinal chemistry Methane Inorganic Chemistry chemistry.chemical_compound Deprotonation chemistry Yield (chemistry) Materials Chemistry Physical and Theoretical Chemistry Carbon |
| Zdroj: | Journal of Organometallic Chemistry. 312:C61-C63 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/0022-328x(86)80331-x |
| Popis: | HgCl 2 reacts with 2 equivalents of (PPh 2 ) 2 CHLi to yield the title compound. The deprotonated dppm ligands are monodentate and bonded through the methine carbon atoms as shown by 31 P and 199 Hg NMR spectroscopy. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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