Synthesis of Lithium Metatianate by Hydrolysis of Mixed Metal Alkoxide Solution

Autor:	Yoshihito Sakurai
Rok vydání:	1992
Předmět:	Butanol Inorganic chemistry chemistry.chemical_element General Chemistry Atmospheric temperature range medicine.disease chemistry.chemical_compound Hydrolysis Grain growth chemistry Alkoxide medicine Lithium Dehydration Titanium
Zdroj:	NIPPON KAGAKU KAISHI. :233-235
ISSN:	2185-0925 0369-4577
DOI:	10.1246/nikkashi.1992.233
Popis:	Hydrous lithium metatitanate (Li2TiO2⋅nH2O) fine particles were formed from the alcoholic solution of lithium and titanium alkoxides. Titanium tetraisopropoxide was added to the butanol or ethanol solution of lithium tert-butoxide, and then the mixed solution was hydrolyzed with H20-i-C2H2OH solution. In the case of Ti/Li mole ratio=0.5, the sharp XRD profiles of Li2TiO3only were observed in the XRD pattern of the precipitate when heattreated at 800°Cfor 1 h. The weight loss of 15% of the precipitate was observed due to dehydration in the temperature range from 100°C to about 800°C, which corresponded to n=1.4 in the chemical formula described above. The remarkable grain growth of the precipita te by the heat-treatment at 800°C for 1 h was recognized in the SEM observation; the wellshaped Li2TiO3 particles of about 200 nm in length was obtained.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c8e3bd87796a6de2ab7263644bb25573 https://doi.org/10.1246/nikkashi.1992.233 Zobrazit plný text záznamu