A novel 3D Ag(I)-MOF: Surfactant-directed syntheses and catalytic degradation of o/m/p-Nitrophenol
| Autor: | Wen-Wen Dong, Jun Zhao, Xue-Qian Wu, Ya-Pan Wu, Guo-Xuan Wen, Dongsheng Li |
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| Rok vydání: | 2016 |
| Předmět: |
Kinetics
Crystal growth 02 engineering and technology 010402 general chemistry 01 natural sciences Medicinal chemistry law.invention Catalysis Inorganic Chemistry Nitrophenol chemistry.chemical_compound Magazine Pulmonary surfactant law Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Aqueous solution Chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 0104 chemical sciences Electronic Optical and Magnetic Materials Ceramics and Composites Degradation (geology) 0210 nano-technology |
| Zdroj: | Journal of Solid State Chemistry. 242:243-247 |
| ISSN: | 0022-4596 |
| Popis: | For the first time, sodium caprylate has been investigated to direct the crystal growth of 3D Ag-MOF, [Ag2(ddcba)(4,4′-bipy)2] (1), constructing from 3,5-(di(2′,5′-dicarboxylphenyl)benozoic acid and 4,4′-bipy. The single crystal diffraction analyses shows that complex 1 possess 3D neutral framework with a three-connected ThSi2 (103-b) topology. Compound 1 exhibits predominant catalytic activity towards the degradation of o-Nitrophenol (ONP), m-Nitrophenol (MNP) and p-Nitrophenol (PNP) in aqueous solution. The kinetics of such catalytic degradation reactions was also studied. |
| Databáze: | OpenAIRE |
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