Dynamic stereochemistry of ligand substitution at a chiral titanium center. Synthesis of asymmetrical halidopseudohalidotitanocene complexes

Autor:	Jean Tirouflet, Jack Besancon, D. Camboli
Rok vydání:	1980
Předmět:	Stereochemistry Ligand Organic Chemistry Substitution (logic) chemistry.chemical_element Center (group theory) Biochemistry Inorganic Chemistry Stereospecificity chemistry Materials Chemistry Dynamic stereochemistry Physical and Theoretical Chemistry Titanium atom Titanium
Zdroj:	Journal of Organometallic Chemistry. 186:C15-C18
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)93831-2
Popis:	Two new ligand exchange reactions (i and ii) at a chiral titanium center have been studied: These two reactions are selective but only the second is stereospecific. Reaction ii is shown to involve retention at the titanium atom. By use of these reaction, the first pairs of asymmetrical halidopseudohalido titanocene complexes have been isolated, and their relative configurations are suggested.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c8bd7848d2bbb98843578c7f13c4d7b7 https://doi.org/10.1016/s0022-328x(00)93831-2 Zobrazit plný text záznamu