A multifunctional 1D Cd-based metal-organic complex for the highly luminescent sensitive detection of Fe3+, CrO42-/Cr2O72-, and nitroaromatic explosives
| Autor: | Dou-Dou Feng, Jie Yang, Dong-Dong Fang, Yu-Di Zhao, Xiaoqing Wang, Liming Fan, Jing Tang |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
Supramolecular chemistry chemistry.chemical_element 02 engineering and technology 010402 general chemistry Photochemistry 01 natural sciences Sensitivity (explosives) Inorganic Chemistry Metal chemistry.chemical_compound Pyridine Materials Chemistry Physical and Theoretical Chemistry Cadmium Aqueous solution 021001 nanoscience & nanotechnology Condensed Matter Physics 0104 chemical sciences Electronic Optical and Magnetic Materials chemistry visual_art Ceramics and Composites visual_art.visual_art_medium 0210 nano-technology Selectivity Luminescence |
| Zdroj: | Journal of Solid State Chemistry. 274:40-46 |
| ISSN: | 0022-4596 |
| DOI: | 10.1016/j.jssc.2019.02.013 |
| Popis: | A novel 1D cadmium-based luminescent metal-organic complex {[Cd(CIP)2(H2O)2]n·2.5H2O} (1) (HCIP=4-(4-carboxylphenyl)− 2,6-di(4-imidazol-1-yl)phenyl)pyridine), has been synthesized through a solvothermal method. The single-crystal X-ray diffraction analysis shows that complex 1 exhibits a 1D chain structure that is further extended to a 3D supramolecular framework by H-bonds and and π-stacking interaction. Luminescence tests suggest that complex 1 displays excellent sensitivity and selectivity to detect Fe3+, CrO42-/Cr2O72-, and a wide range of nitroaromatic explosives. It is the first example of a Cd-based LMOC as luminescent probe to detect Fe3+, CrO42-/Cr2O72- in aqueous solution and nitroaromatic explosives in both liquid and vapor phases. |
| Databáze: | OpenAIRE |
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