Ternary phthalocyanato Hf(iv) and Zr(iv) polyoxometalate complexes

Autor: Lynn C. Francesconi, Kemakorn Ithisuphalap, Charles Michael Drain, Benjamin P. Burton-Pye, Raihan Saleh, Ivana Radivojevic
Rok vydání: 2013
Předmět:
Zdroj: RSC Advances. 3:2174
ISSN: 2046-2069
DOI: 10.1039/c2ra22903j
Popis: Ternary phthalocyanine–metal–polyoxometalate (Pc–M–POM) complexes were synthesized and characterized. Group (IV) Hf or Zr ions reside outside the plane of the macrocycle and are coordinated to both the phthalocyanine and the lacunary polyoxometalate. The metal ions mediate the electronic communication between the Pc and the POM.
Databáze: OpenAIRE