Steam reforming of bagasse to hydrogen and synthesis gas using ruthenium promoted Ni Fe/γ Al2O3nano-catalysts
| Autor: | Ali Reza Karimi, Ahmad Tavasoli, Omid Norouzi, Sajedeh Jafarian |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Materials science
Hydrogen Renewable Energy Sustainability and the Environment 020209 energy Inorganic chemistry Energy Engineering and Power Technology chemistry.chemical_element 02 engineering and technology 021001 nanoscience & nanotechnology Condensed Matter Physics Ruthenium Catalysis Steam reforming chemistry.chemical_compound Fuel Technology chemistry Chemisorption 0202 electrical engineering electronic engineering information engineering 0210 nano-technology Carbon Syngas Carbon monoxide |
| Zdroj: | International Journal of Hydrogen Energy. 42:5505-5512 |
| ISSN: | 0360-3199 |
| DOI: | 10.1016/j.ijhydene.2016.05.261 |
| Popis: | Bagasse conversion to H 2 , CO and light gaseous hydrocarbons was performed in a batch micro reactor under 850 °C and atmospheric pressure in the presence of unpromoted and ruthenium promoted Ni Fe/γ Al 2 O 3 nano catalysts. The nano catalysts were prepared with 12 wt.% Ni, 6 wt.% Fe and 0.5 to 2 wt.% Ru loadings via microemulsion technique. The catalysts were extensively characterized using ICP, XRD, TPR, BET, TEM and H 2 chemisorption techniques. XRD patterns confirmed formation of Ni Fe alloys on the catalysts. Ruthenium increased dispersion of active metal clusters by 44.6% and consequently improved the reducibility of the catalysts. The addition of 1 wt.% Ru increased the total gas yield, the yield of hydrogen, the yield of carbon monoxide and the carbon conversion efficiency by 34.2%, 35.9%, 33.54% and 44% respectively. |
| Databáze: | OpenAIRE |
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