Hypervalent Iodine(III) Reagent-promoted Rearrangement and Subsequent Oxidative Ring Cleavage of Cyclic 2,3-Epoxy-1-alcohol Derivatives

Autor:	Eri Fujii, Hiromichi Fujioka, Yasuyuki Kita, Ryoko Inoguchi, Satoshi Matsuda, Kayoko Hata, Shinji Kitagaki
Rok vydání:	2005
Předmět:	Pharmacology Organic Chemistry Hypervalent molecule chemistry.chemical_element Alcohol Oxidative phosphorylation Cleavage (embryo) Ring (chemistry) Iodine Medicinal chemistry Analytical Chemistry chemistry.chemical_compound chemistry Cascade reaction Reagent
Zdroj:	HETEROCYCLES. 66:309
ISSN:	0385-5414
DOI:	10.3987/com-05-s(k)23
Popis:	The rearrangements of 2,3-epoxy alcohol derivatives were achieved using the hypervalent iodine(III) reagent, phenyliodine(III) b:is(trifluoroacetate) (PIFA). In the case of 2,3-epoxy alcohols subsequent oxidative ring cleavage occurred to give ω-formylalkanoic acids.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c88fd953ed1d2a94f25596eead4ae9ad https://doi.org/10.3987/com-05-s(k)23 Zobrazit plný text záznamu