Enantioselective cyanation of propargylic C–H bonds via cooperative photoredox and copper catalysis

Autor:	Yunshun Deng, Ronghua Lu, Pinhong Chen, Guosheng Liu
Rok vydání:	2023
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 59:4656-4659
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d3cc00410d
Popis:	An asymmetric cyanation of propargylic C–H bonds via a copper-catalyzed radical relay has been developed, in which the propargylic radical was formed via a photoredox-catalyzed intramolecular 1,5-HAT process.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c889f0cbd5202a83e5f681a5f804c2be https://doi.org/10.1039/d3cc00410d Zobrazit plný text záznamu