Femto-picosecond relaxation of triazole-bridged bis(zinc porphyrin)
Autor: | Vladimir S. Tyurin, Ivan V. Shelaev, Fedor E. Gostev, Yu. P. Yashchuk, V. A. Nadtochenko, Irina P. Beletskaya, K. M. Mikhailov |
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Rok vydání: | 2014 |
Předmět: | |
Zdroj: | High Energy Chemistry. 48:276-281 |
ISSN: | 1608-3148 0018-1439 |
Popis: | The femtosecond dynamics of excitation relaxation has been revealed for the zinc porphyrin dimer using the pump-probe technique. The data obtained have been analyzed with the use of quantum-chemical calculations. The excitation relaxation dynamics shows that systems of this kind hold promise as models for investigation of photosystems and development of artificial analogues of natural photosynthetic centers. A model has been proposed to explain the found coherent dynamics of exciton bands. |
Databáze: | OpenAIRE |
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