Oxidative N-nitration of secondary amines

Autor:	Dmitry L. Lipilin, G. V. Pokhvisneva, Oleg V. Anikin, A. V. Mezhenin, Vladimir A. Tartakovsky
Rok vydání:	2009
Předmět:	chemistry.chemical_classification Solvent chemistry.chemical_compound Nitrite anion chemistry Nitration Nitrosation Salt (chemistry) Organic chemistry Amine gas treating General Chemistry Oxidative phosphorylation
Zdroj:	Russian Chemical Bulletin. 58:2043-2046
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-009-0280-3
Popis:	Reaction of secondary amines with the nitrite anion assisted by diacetoxyiodobenzene results in respective N-nitroamines. It is the first example of oxidative nitration of the amino group. N-Nitrosoamines are by-products. The yields and the ratio of the nitration and nitrosation products depend on the nature of the starting amine, cation of the salt used, and the solvent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c86e7bb3871e175d7cac1804f0148067 https://doi.org/10.1007/s11172-009-0280-3 Zobrazit plný text záznamu Full text from SpringerLink