Dimerization of Phosphasilaferracycles: Formation and Structures of Isomeric Fe2Si2P2 Six-Membered Metallacylcles

Autor:	Masaaki Okazaki, Kazuyuki Satoh, Hiroshi Ogino, Kyeong A. Jung, Hiromi Tobita
Rok vydání:	2004
Předmět:	Inorganic Chemistry Crystallography chemistry.chemical_compound Chemistry Product (mathematics) Organic Chemistry Acetone Irradiation Physical and Theoretical Chemistry
Zdroj:	Organometallics. 23:1971-1973
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om034264g
Popis:	Irradiation of Cp(CO)2FeSiMe2PPh2 led to formation of an isomeric mixture of Cp2Fe2(CO)2[μ2-{κ2(Si,P)-Me2SiPPh2}]2 through generation of Cp(CO)Fe{κ2(Si,P)-Me2SiPPh2} and its successive dimerization. The three-membered-ring complex reacted smoothly with acetone to give the insertion product Cp(CO)Fe{κ2(Si,P)-Me2SiOCMe2PPh2}.
Databáze:	OpenAIRE
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