A Synthesis of AB-Ring Model System of Taxane Framework by Way of Intramolecular Knoevenagel Cyclization

Autor:	Yu‐ichirou Tani, Teruaki Mukaiyama, Ayako Ohno, Shouhei Imachi, Hidehiro Arai
Rok vydání:	2002
Předmět:	Chemistry Intramolecular force Model system Knoevenagel condensation General Chemistry Ring (chemistry) Medicinal chemistry
Zdroj:	Chemistry Letters. 31:92-93
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.2002.92
Popis:	Methyl 1,2-dialkoxy-11,11-dimethyl-9-oxobicyclo[5.3.1]-undec-7-en-8-carboxylate 19 was synthesized by cesium fluoride-mediated intramolecular Knoevenagel reaction of methyl 4-(1,8-dialkoxy-2,2-dimethyl-3-oxocyclooctyl)-3-oxobutanonate 18.
Databáze:	OpenAIRE
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