Heteroatom-Substituted Microporous AFI and ATS Structured Materials for Hydrocarbon Trap: An Insight into the Aluminophosphate Framework−Toluene Interaction
| Autor: | Tatsuya Okubo, Robert W. Dorner, Malek Deifallah, F. Cora, Shanmugam Palani Elangovan, C. R. A. Catlow, Gopinathan Sankar |
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| Rok vydání: | 2008 |
| Předmět: |
Chemistry
Heteroatom Inorganic chemistry Microporous material Molecular sieve Toluene Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound General Energy Chemical engineering Physical and Theoretical Chemistry Zeolite Benzene Isomerization Powder diffraction |
| Zdroj: | The Journal of Physical Chemistry C. 112:4187-4194 |
| ISSN: | 1932-7455 1932-7447 |
| DOI: | 10.1021/jp074121y |
| Popis: | We report the synthesis of different heteroatom-substituted aluminophosphates with AFI and ATS topology and their ability to store toluene in wet and dry conditions. By mixing Zeolite A with the material to be tested, it was possible to obtain identical results in both wet and dry conditions. Molecular dynamics simulations coupled with high-resolution X-ray powder diffraction studies allowed us to obtain detailed information on the toluene-framework interactions. |
| Databáze: | OpenAIRE |
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