Quantum-chemical investigation of the mechanisms of reactions involving nucleophilic addition to acetylene. 4. Study of reactions in the acetylene-LIOH system

Autor:	O. Yu. Dolgunicheva, Boris A. Trofimov, F. S. Dubnikova, N. M. Vitkovskaya
Rok vydání:	1988
Předmět:	chemistry.chemical_compound Nucleophilic addition chemistry Nucleophile Acetylene chemistry.chemical_element Hydroxide Molecule Lithium General Chemistry Triple bond Photochemistry Lithium hydroxide
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 37:1841-1846
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00962500
Popis:	1. The predominant direction of the reaction of acetylene with a molecule of lithium hydroxide in both the dissociated and undissociated states is the formation of the molecular π complex C2H2· LiOH. 2. The formation of the complex C2H2· LiOH is accompanied by significant lowering of the energy levels of the vacant π orbitals of acetylene, which creates favorable conditions for nucleophilic attack on the triple bond.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c856301ae732933a18adfdd4b1b97317 https://doi.org/10.1007/bf00962500 Zobrazit plný text záznamu Full text from SpringerLink